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Sulfidkontraktion <i>via</i> alkylative Kupplung: Eine methode zur darstellung von β‐dicarbonylderivaten. Über synthetische methoden, 1. Mitteilung
Helvetica Chimica Acta · 1971 · Vol. 54(2) · pp. 710–734
Martin M. Roth✉(Analytisches Laboratorium)Paul Dubs(Analytisches Laboratorium)Erwin Götschi(Analytisches Laboratorium)Albert Eschenmoser(Analytisches Laboratorium)
Abstract
Abstract The experiments described in reaction schemes 1–12 indicate that sulfide contraction via alkylative coupling (see scheme p. 729) is a potentially general method for the synthesis of secondary vinylogous amides and enolizable β‐dicarbonyl compounds.
Advanced Synthetic Organic ChemistryAsymmetric Synthesis and CatalysisChemical synthesis and alkaloidsChemistryStereochemistryMedicinal chemistry
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