articleTop 1% cited
Deposition of Gold Clusters on Porous Coordination Polymers by Solid Grinding and Their Catalytic Activity in Aerobic Oxidation of Alcohols
Chemistry - A European Journal · 2008 · Vol. 14(28) · pp. 8456–8460
Tamao Ishida✉(Tokyo Metropolitan University)Megumi Hamano Nagaoka(Tokyo Metropolitan University)Tomoki Akita(Japan Science and Technology Agency)Masatake Haruta(Tokyo Metropolitan University)
Abstract
Gold clusters were deposited in a narrow size distribution on porous coordination polymers (PCPs) by solid grinding with volatile dimethyl AuIII acetylactonate. The mean diameter could be minimized down to 1.5 nm for Al-containing PCP. Gold clusters on PCPs showed noticeably high catalytic activity in the aerobic oxidation of alcohols. Product selectivity was tunable by the selection of PCP supports in benzyl alcohol oxidation.
Catalytic Processes in Materials ScienceNanoporous metals and alloysNanomaterials for catalytic reactionsBenzyl alcoholAlcohol oxidationCatalysisGrindingPolymerSelectivityDeposition (geology)Coordination polymerPorosityChemistry
Funding
- Chongqing University of Arts and Sciences
- Tokyo Metropolitan University
Citations
478
FWCI
15.33
field-weighted impact
References
57
Percentile
99%
vs. same field & year
Citations per year
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A Rationale for the Large Breathing of the Porous Aluminum Terephthalate (MIL‐53) Upon Hydration
Chemistry - A European Journal · 2004 · 2,093 citations
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Chemical Reviews · 2003 · 12,285 citations
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Funktionale poröse Koordinationspolymere
Angewandte Chemie · 2004 · 1,337 citations
Probing the Lewis Acidity and Catalytic Activity of the Metal–Organic Framework [Cu<sub>3</sub>(btc)<sub>2</sub>] (BTC=Benzene‐1,3,5‐tricarboxylate)
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