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Large-scale delamination of multi-layers transition metal carbides and carbonitrides “MXenes”

Dalton Transactions · 2015 · Vol. 44(20) · pp. 9353–9358
Michael NaguibRaymond R. UnocicBeth L. ArmstrongJagjit Nanda

Abstract

Herein we report on a general approach to delaminate multi-layered MXenes using an organic base to induce swelling that in turn weakens the bonds between the MX layers. Simple agitation or mild sonication of the swollen MXene in water resulted in the large-scale delamination of the MXene layers. The delamination method is demonstrated for vanadium carbide and titanium carbonitride MXenes.

MXene and MAX Phase Materials2D Materials and ApplicationsGraphene research and applicationsMXenesDelamination (geology)Materials scienceTitanium carbideCarbideSwellingComposite materialNanoscopic scaleNanotechnologyGeology

Funding

  • Office of Science
  • Laboratory Directed Research and Development
  • Oak Ridge National Laboratory
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