article Open AccessTop 1% cited
Large-scale delamination of multi-layers transition metal carbides and carbonitrides “MXenes”
Dalton Transactions · 2015 · Vol. 44(20) · pp. 9353–9358
Michael Naguib✉(Oak Ridge National Laboratory)Raymond R. Unocic(Oak Ridge National Laboratory)Beth L. Armstrong(Oak Ridge National Laboratory)Jagjit Nanda(Oak Ridge National Laboratory)
Abstract
Herein we report on a general approach to delaminate multi-layered MXenes using an organic base to induce swelling that in turn weakens the bonds between the MX layers. Simple agitation or mild sonication of the swollen MXene in water resulted in the large-scale delamination of the MXene layers. The delamination method is demonstrated for vanadium carbide and titanium carbonitride MXenes.
MXene and MAX Phase Materials2D Materials and ApplicationsGraphene research and applicationsMXenesDelamination (geology)Materials scienceTitanium carbideCarbideSwellingComposite materialNanoscopic scaleNanotechnologyGeology
Funding
- Office of Science
- Laboratory Directed Research and Development
- Oak Ridge National Laboratory
Citations
907
FWCI
14.13
field-weighted impact
References
38
Percentile
99%
vs. same field & year
Citations per year
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References
Two-Dimensional Transition Metal Carbides
ACS Nano · 2012 · 4,553 citations
Intercalation and delamination of layered carbides and carbonitrides
Nature Communications · 2013 · 2,723 citations
Two‐Dimensional Nanocrystals Produced by Exfoliation of Ti<sub>3</sub>AlC<sub>2</sub>
Advanced Materials · 2011 · 11,128 citations
Transparent Conductive Two-Dimensional Titanium Carbide Epitaxial Thin Films
Chemistry of Materials · 2014 · 1,628 citations
Electric Field Effect in Atomically Thin Carbon Films
Science · 2004 · 65,340 citations
Novel Electronic and Magnetic Properties of Two‐Dimensional Transition Metal Carbides and Nitrides
Advanced Functional Materials · 2012 · 1,905 citations
One-step synthesis of nanocrystalline transition metal oxides on thin sheets of disordered graphitic carbon by oxidation of MXenes
Chemical Communications · 2014 · 775 citations
High-yield production of graphene by liquid-phase exfoliation of graphite
Nature Nanotechnology · 2008 · 6,141 citations
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