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The Heck Reaction in Ionic Liquids: A Multiphasic Catalyst System
Organic Letters · 1999 · Vol. 1(7) · pp. 997–1000
Adrian J. Carmichael✉(Queen's University Belfast)Martyn J. Earle(Queen's University Belfast)John D. Holbrey(Queen's University Belfast)Paul B. McCormac(Queen's University Belfast)Kenneth R. Seddon(Queen's University Belfast)
Abstract
Heck coupling of aryl halides or benzoic anhydride with alkenes can be performed with excellent yields in room-temperature ionic liquids, which provide a medium that dissolves the palladium catalyst and allows the product and byproducts to be easily separated. Consequently, the catalyst and ionic liquid can be recycled and reused.
Ionic liquids properties and applicationsCatalytic Cross-Coupling ReactionsInnovative Microfluidic and Catalytic Techniques InnovationChemistryCatalysisIonic liquidHeck reactionHalideArylPalladiumIonic bondingOrganic chemistryPalladium catalyst
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References
Selective Catalytic Hydrodimerization of 1,3-Butadiene by Palladium Compounds Dissolved in Ionic Liquids
Organometallics · 1998 · 293 citations
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