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Ferroelectric BiFeO3 X-ray and neutron diffraction study

Journal of Physics and Chemistry of Solids · 1971 · Vol. 32(6) · pp. 1315–1320

J.M. Moreau✉(Missouri University of Science and Technology)Christine Michel(Missouri University of Science and Technology)Robert Gerson(Missouri University of Science and Technology)W. J. James(Missouri University of Science and Technology)

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Multiferroics and related materialsNeutron diffractionFerroelectricityOctahedronCrystallographyLattice constantPowder diffractionSingle crystalDiffractionNeutronPerovskite (structure)

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Systematic trends of the 57Fe Mössbauer isomer shifts in (FeOn) and (FeFn) polyhedra. Evidence of a new correlation between the isomer shift and the inductive effect of the competing bond T-X (→ Fe) (where X is O or F and T any element with a formal positive charge)