articleTop 10% cited
One- and two-electron pathways in the electrocatalytic reduction of CO<sub>2</sub>by fac-Re(bpy)(CO)<sub>3</sub>Cl (bpy = 2,2′-bipyridine)
Journal of the Chemical Society Chemical Communications · 1985 · pp. 1414–1416
Abstract
The cyclic voltammetry of fac-Re(bpy)(CO)3Cl (bpy = 2,2′-bipyridine) and of the intermediate complexes formed by bulk electrolysis in MeCN solution in the presence and absence of CO2 has been interpreted in terms of two different electrocatalytic pathways for the reduction of CO2 to Co, one involving an initial one-electron reduction and the other an initial two-electron reduction.
CO2 Reduction Techniques and CatalystsCarbon dioxide utilization in catalysisElectrocatalysts for Energy ConversionChemistryCyclic voltammetryElectrolysisReduction (mathematics)Bulk electrolysisBipyridineElectrocatalyst2,2'-BipyridineElectronOne-electron reduction
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7.35
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