articleTop 10% cited
Self-Assembly of 2,8,14,20-Tetraisobutyl-5,11,17,23-tetrahydroxyresorc[4]arene
European Journal of Organic Chemistry · 1999 · Vol. 1999(9) · pp. 2257–2262
T. Gerkensmeier(Kiel University)Waldemar IwanekCeno Agena(Bielefeld University)Roland Fröhlich(University of Münster)Sirpa Kotila(University of Jyväskylä)Christian Näther(Kiel University)Jochen Mattay✉
Abstract
We report herein the observation of a hexameric structure of a hydroxyresorc[4]arene in the solid state, enclosing a large interior space. This artificial molecular container is stabilized only by hydrogen bonds. The tendency to form aggregates in solution is demonstrated mainly by means of ESI-MS methods.
Supramolecular Chemistry and ComplexesMolecular Sensors and Ion DetectionCrystallography and molecular interactionsChemistrySelf-assemblyHydrogen bondSolid-stateContainer (type theory)CalixareneCrystallographyStereochemistryPolymer chemistryMolecule
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References
Calixarenes, Macrocycles with (Almost) Unlimited Possibilities
Angewandte Chemie International Edition in English · 1995 · 1,932 citations
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