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Catalysis with N‐Heterocyclic Carbenes under Oxidative Conditions

Chemistry - A European Journal · 2013 · Vol. 19(15) · pp. 4664–4678
Suman De SarkarAnup BiswasRamesh C. SamantaArmido Studer

Abstract

This Concept article discusses the potential of oxidative carbene catalysis in synthesis and comprehensively covers pioneering studies as well as recent developments. Oxidative carbene catalysis can be conducted by using inorganic and organic oxidants. Applications in cascade processes, in enantioselective catalysis, and also in natural product synthesis are discussed.

N-Heterocyclic Carbenes in Organic and Inorganic ChemistryCatalytic Cross-Coupling ReactionsSynthetic Organic Chemistry MethodsCarbeneCatalysisEnantioselective synthesisOxidative phosphorylationChemistryCombinatorial chemistryOrganocatalysisNatural productOxidative additionOrganic chemistry
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499
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101
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References
Methods of Reactivity Umpolung
Angewandte Chemie International Edition in English · 1979 · 1,228 citations
Methoden der Reaktivitätsumpolung
Angewandte Chemie · 1979 · 543 citations
Enantioselective Conjugate Additions
Tetrahedron · 2000 · 810 citations
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