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Palladium-Catalyzed Arylation of Electron-Rich Heterocycles with Aryl Chlorides
Organic Letters · 2007 · Vol. 9(8) · pp. 1449–1451
Hendrich A. Chiong✉(University of Houston)Olafs Daugulis(University of Houston)
Abstract
[reaction: see text] Palladium-catalyzed C-H activation: cheap aryl chlorides can now be used for the arylation of a wide variety of electron-rich heterocycles. The key to the success of this reaction is the use of a bulky, electron-rich phosphine ligand. No copper additives are needed.
Catalytic Cross-Coupling ReactionsCatalytic C–H Functionalization MethodsChemical synthesis and alkaloidsChemistryPalladiumArylCatalysisCombinatorial chemistryElectronOrganic chemistryMedicinal chemistryAlkyl
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References
Palladium-Catalyzed Coupling Reactions of Aryl Chlorides
Angewandte Chemie International Edition · 2002 · 2,674 citations
Palladium-Catalyzed Arylation of Azole Compounds with Aryl Halides in the Presence of Alkali Metal Carbonates and the Use of Copper Iodide in the Reaction
Bulletin of the Chemical Society of Japan · 1998 · 465 citations
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