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Plasmon Hybridization in Nanoparticle Dimers

Nano Letters · 2004 · Vol. 4(5) · pp. 899–903
Peter NordlanderChris OubreEmil ProdanK. LiMark I. Stockman

Abstract

We apply the recently developed plasmon hybridization method to nanoparticle dimers, providing a simple and intuitive description of how the energy and excitation cross sections of dimer plasmons depend on nanoparticle separation. We show that the dimer plasmons can be viewed as bonding and antibonding combinations, i.e., hybridization of the individual nanoparticle plasmons. The calculated plasmon energies are compared with results from FDTD simulations.

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchNanoparticle-Based Drug DeliveryPlasmonAntibonding molecular orbitalNanoparticleMaterials scienceDimerLocalized surface plasmonExcitationMolecular physicsNanotechnologyChemical physics
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