articleTop 1% cited
(NHC)Cu<sup>I</sup> (NHC = N-Heterocyclic Carbene) Complexes as Efficient Catalysts for the Reduction of Carbonyl Compounds
Organometallics · 2004 · Vol. 23(5) · pp. 1157–1160
Harneet Kaur✉(University of New Orleans)Fabiano Kauer Zinn(University of New Orleans)Edwin D. Stevens(University of New Orleans)Steven P. Nolan(University of New Orleans)
Abstract
The hydrosilylation of various ketones is mediated by an imidazolium salt/Cu(I) salt system or by a well-defined (NHC)CuCl (NHC = N-heterocyclic carbene) catalyst precursor system. Reactions are conducted at room temperature. The synthesis and characterization of well-defined (NHC)CuCl complexes are described.
N-Heterocyclic Carbenes in Organic and Inorganic ChemistryCatalytic Cross-Coupling ReactionsAsymmetric Hydrogenation and CatalysisCarbeneChemistryHydrosilylationCatalysisSalt (chemistry)Medicinal chemistryOrganic chemistryPolymer chemistry
Citations
302
FWCI
11.40
field-weighted impact
References
14
Percentile
99%
vs. same field & year
Citations per year
Cited by
Synthesis, Structure, and Alkyne Reactivity of a Dimeric (Carbene)copper(I) Hydride
Organometallics · 2004 · 329 citations
Stability and reactivity of N-heterocyclic carbene complexes
Coordination Chemistry Reviews · 2004 · 982 citations
Synthesis of Well-Defined <i>N</i>-Heterocyclic Carbene Silver(I) Complexes
Organometallics · 2005 · 335 citations
Percent buried volume for phosphine and N-heterocyclic carbene ligands: steric properties in organometallic chemistry
Chemical Communications · 2010 · 1,074 citations
References
Mild and Efficient Copper-Catalyzed Amination of Aryl Bromides with Primary Alkylamines
Organic Letters · 2003 · 388 citations
Citation Network
How this paper connects to the literature. Drag to explore, click any node to open that paper.