article

Transition metal-catalysed N-alkylation of amines by alcohols

Journal of the Chemical Society Chemical Communications · 1981 · pp. 611–611

Ronald Grigg✉T. R. B. MITCHELLSomyote SutthivaiyakitNgampong Tongpenyai

Abstract

Primary and secondary alcohols effect alkylation of primary and secondary amines in the presence of rhodium, iridium, and ruthenium compounds at ⩽ 100 °C, whereby selective monoalkylation of primary amines can be achieved and heterocyclic rings can be constructed by both inter- and intra-molecular processes.

Asymmetric Hydrogenation and Catalysis Carbon dioxide utilization in catalysis Synthetic Organic Chemistry MethodsAlkylationPrimary (astronomy)ChemistryRhodiumIridiumRutheniumTransition metalOrganic chemistryMetalCatalysis

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