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New methods and reagents in organic synthesis. 14. A simple efficient preparation of methyl esters with trimethylsilyldiazomethane (TMSCHN2) and its application to gas chromatographic analysis of fatty acids.
Chemical and Pharmaceutical Bulletin · 1981 · Vol. 29(5) · pp. 1475–1478
Norio Hashimoto✉(Nagoya City University)Toyohiko Aoyama(Nagoya City University)Takayuki Shioiri(Nagoya City University)
Abstract
Trimethylsilyldiazomethane (TMSCHN2), known as a stable and safe substitute for highly toxic and explosive diazomethane in the Arndt-Eistert synthesis and homologation of carbonyl compounds, has smoothly reacted with various carboxylic acids in methanolic benzene solution to give the corresponding methyl esters in excellent yields.
Chemistry and Chemical EngineeringVarious Chemistry Research TopicsAnalytical Chemistry and ChromatographyChemistryDiazomethaneReagentOrganic chemistryExplosive materialChromatographyGas chromatographyBenzene
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