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Preparation and use of tetra-n-butylammonium per-ruthenate (TBAP reagent) and tetra-n-propylammonium per-ruthenate (TPAP reagent) as new catalytic oxidants for alcohols
Journal of the Chemical Society Chemical Communications · 1987 · pp. 1625–1625
William P. Griffith✉(St. Mark's Hospital)Steven V. Ley(St. Mark's Hospital)Gwynne P. Whitcombe(St. Mark's Hospital)Andrew D. White(St. Mark's Hospital)
Abstract
Tetra-n-butylammonium per-ruthenate (Bun4N)(RuO4) and tetra-n-propylammonium per-ruthenate (Prn4N)(RuO4), with N-methylmorpholine N-oxide, function as mild catalytic oxidants for the high yield conversion of alcohols to aldehydes and ketones and are competitive with more conventional reagents.
Oxidative Organic Chemistry ReactionsChemical Synthesis and ReactionsInorganic and Organometallic ChemistryReagentTetraChemistryCatalysisYield (engineering)Medicinal chemistryOrganic chemistryMaterials science
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