Ultrahigh pressure diamond-anvil cell and several semiconductor phase transition pressures in relation to the fixed point pressure scale

Abstract

A diamond-anvil type optical cell of improved design has produced static pressures in gasketed samples up to 500 kilobar as measured by the ruby fluorescence technique. The ruby R1 line pressure shift is linear to 291 kilobar, and the maximum measured shift is extrapolated to 500 kilobar assuming continued linearity of the pressure dependence. The ultimate pressure capability of this diamond cell has not been established. Transition pressures in the semiconductors Si, ZnSe, ZnS, and GaP measured by the ruby method indicate that the revised 1970 fixed point scale and the ruby (NaCl) scale diverge above 135 kilobar and disagreement may be by as much as a factor of 2 in the 500 kilobar range with the ruby scale defining the lower pressure.