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Palladium-catalyzed New Carbon-Phosphorus Bond Formation
Bulletin of the Chemical Society of Japan · 1982 · Vol. 55(3) · pp. 909–913
Toshikazu Hirao✉(Osaka University)Toshio Masunaga(Osaka University)Naoto Yamada(Osaka University)Yoshiki Ohshiro(Osaka University)Toshio Agawa(Osaka University)
Abstract
Abstract Dialkyl arylphosphonates are prepared by the palladium-catalyzed reaction of aryl bromides with dialkyl phosphite in the presence of triethylamine. The similar treatment of vinyl bromides gives dialkyl vinylphosphonates stereoselectively.
Organophosphorus compounds synthesisFluorine in Organic ChemistryCatalytic Cross-Coupling ReactionsChemistryPalladiumCatalysisPhosphorusCarbon fibersOrganic chemistry
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