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Activation and Reactivity of (NHC)Pd(allyl)Cl (NHC = N-Heterocyclic Carbene) Complexes in Cross-Coupling Reactions

Organometallics · 2002 · Vol. 21(25) · pp. 5470–5472

Mihai S. Viciu✉(University of New Orleans)R.F. Germaneau(University of New Orleans)Oscar Navarro(University of New Orleans)Edwin D. Stevens(University of New Orleans)Steven P. Nolan(University of New Orleans)

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Abstract

Mononuclear palladium-allyl complexes bearing one N-heterocyclic carbene (NHC) ligand have been synthesized. These complexes offer a straightforward entryway into a number of catalytic cycles by simple action of a base.

Catalytic Cross-Coupling Reactions N-Heterocyclic Carbenes in Organic and Inorganic Chemistry Synthetic Organic Chemistry MethodsCarbeneChemistryLigand (biochemistry)Reactivity (psychology)PalladiumCatalysisMedicinal chemistryCoupling reactionBase (topology)Stereochemistry

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