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Supramolecular Isomerism in Coordination Polymers: Conformational Freedom of Ligands in [Co(NO<sub>3</sub>)<sub>2</sub>(1,2‐bis(4‐pyridyl)ethane)<sub>1.5</sub>]<sub><i>n</i></sub>

Angewandte Chemie International Edition in English · 1997 · Vol. 36(9) · pp. 972–973

Tracy L. Hennigar✉(Saint Mary's University)Donald C. MacQuarrie✉(Saint Mary's University)Pierre Losier✉(Saint Mary's University)Robin D. Rogers(University of Alabama)Michael J. Zaworotko✉(Saint Mary's University)

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Abstract

Bilayers or open-framework ladder structure? Which supramolecular isomer is formed from Co(NO3)2 and the nonrigid spacer 1,2-bis(2-pyridyl)ethane depends on the crystallization conditions. The open-framework coordination polymer contains large, square cavities of 10 × 10 Å. A section of the bilayer motif is shown on the right.

Metal-Organic Frameworks: Synthesis and Applications Crystal structures of chemical compounds Crystallography and molecular interactionsSupramolecular chemistryCrystallographyPolymerChemistrySupramolecular polymersBilayerCrystallizationStereochemistryCrystal structureMembrane

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References

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Interpenetrating diamondoid frameworks of silver(<scp>I</scp>) cations linked by N,N′-bidentate molecular rods

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Supramolecular Isomerism in Coordination Polymers: Conformational Freedom of Ligands in [Co(NO<sub>3</sub>)<sub>2</sub>(1,2‐bis(4‐pyridyl)ethane)<sub>1.5</sub>]<sub><i>n</i></sub> · Scinovex