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Neutral Nickel(II)-Based Catalysts for Ethylene Polymerization
Organometallics · 1998 · Vol. 17(15) · pp. 3149–3151
Chunming Wang✉(California Institute of Technology)Stefan Friedrich(California Institute of Technology)Todd R. Younkin(California Institute of Technology)Robert T. Li(California Institute of Technology)Robert H. Grubbs(California Institute of Technology)Donald A. Bansleben(California Institute of Technology)Michael W. Day(California Institute of Technology)
Abstract
Neutral salicylaldiminato Ni(II) complexes have been synthesized, and their structure has been confirmed by an X-ray analysis of complex 4e. These compounds are active catalysts for the polymerization of ethylene under mild conditions in the presence of a phosphine scavenger such as Ni(COD)2 or B(C6F5)3.
Organometallic Complex Synthesis and CatalysisAsymmetric Hydrogenation and CatalysisCarbon dioxide utilization in catalysisChemistryScavengerCatalysisEthylenePhosphineNickelPolymerizationPolymer chemistryPhotochemistryOrganic chemistry
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References
Electrophilic Metal Precursors and a β-Diimine Ligand for Nickel(II)- and Palladium(II)-Catalyzed Ethylene Polymerization
Organometallics · 1997 · 345 citations
A new nickel complex for the oligomerization of ethylene
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