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A Road Map to Stable, Soluble, Easily Crystallized Pentacene Derivatives

Organic Letters · 2001 · Vol. 4(1) · pp. 15–18
John E. AnthonyDavid L. EatonSean Parkin

Abstract

[structure: see text] A series of 6,13-disubstituted pentacenes, in which the substituents are functionalized ethyne units, were synthesized and analyzed by X-ray crystallography. The resulting pentacene derivatives were highly soluble and oxidatively stable and exhibited a significant amount of pi-stacking in the crystal.

Organic Electronics and PhotovoltaicsSynthesis and Properties of Aromatic CompoundsPorphyrin and Phthalocyanine ChemistryPentaceneChemistryStackingCrystallographyCrystal structureCrystal (programming language)StereochemistryCombinatorial chemistryOrganic chemistryThin-film transistor
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