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A General Palladium-Catalyzed Coupling of Aryl Bromides/Triflates and Thiols
Organic Letters · 2004 · Vol. 6(24) · pp. 4587–4590
Abstract
We have developed an efficient palladium-catalyzed carbon-sulfur bond formation reaction of aryl bromides, triflates, and activated aryl chloride. Using this protocol, we have shown tolerance to a wide variety of aryl thiols and alkyl thiols that can also be used as sulfide equivalents. [reaction: see text]
Sulfur-Based Synthesis TechniquesCatalytic C–H Functionalization MethodsCatalytic Cross-Coupling ReactionsChemistryArylPalladiumCatalysisAlkylSulfideSulfurChlorideCoupling reactionHalide
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Cited by
The First N-Heterocyclic Carbene-Based Nickel Catalyst for C−S Coupling
Organic Letters · 2007 · 352 citations
References
The Palladium Catalyzed Nucleophilic Substitution of Aryl Halides by Thiolate Anions
Bulletin of the Chemical Society of Japan · 1980 · 405 citations
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