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Chemistry of Thiacalixarenes
European Journal of Organic Chemistry · 2004 · Vol. 2004(8) · pp. 1675–1692
Pavel Lhoták✉(University of Chemistry and Technology, Prague)
Abstract
Abstract Thiacalixarenes — new members of the calixarene family — are very promising molecules with many potential applications in supramolecular chemistry. The presence of four sulfur atoms in the place of methylene groups imparts many novel features and properties to these molecules. This review deals with the chemistry of thiacalixarenes, and by comparision with “classical” calixarenes, emphasizes their differences in reactivity, unusual conformational preferences and modified complexation abilities. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)
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References
Facile synthesis of p-tert-butylthiacalix[4]arene by the reaction of p-tert-butylphenol with elemental sulfur in the presence of a base
Tetrahedron Letters · 1997 · 565 citations
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