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Benzotetramisole: A Remarkably Enantioselective Acyl Transfer Catalyst
Organic Letters · 2006 · Vol. 8(7) · pp. 1351–1354
Vladimir B. Birman✉(University of Washington)Ximin Li(Washington University in St. Louis)
Abstract
[reaction: see text] A commercially available pharmaceutical, tetramisole, was found to be a competent enantioselective acylation catalyst. Its benzannellated analogue, benzotetramisole (BTM), produced outstanding enantioselectivities in kinetic resolution of secondary benzylic alcohols.
Asymmetric Synthesis and CatalysisEnzyme Catalysis and ImmobilizationAsymmetric Hydrogenation and CatalysisEnantioselective synthesisChemistryCatalysisCombinatorial chemistryOrganic chemistryStereochemistry
MeSH terms
Benzyl AlcoholsCatalysisKineticsStereoisomerismTetramisoleMolecular Structure
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A Survey of the Role of Noncovalent Sulfur Interactions in Drug Design
Journal of Medicinal Chemistry · 2015 · 751 citations
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