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Synthesis and characterization of two new classes of ruthenium(III)-sulfoxide complexes with nitrogen donor ligands (L): Na[trans-RuCl4(R2SO)(L)] and mer, cis-RuCl3(R2SO)(R2SO)(L). The crystal structure of Na[trans-RuCl4(DMSO)(NH3)] · 2DMSO, Na[trans-RuCl4(DMSO)(Im)] · H2O, Me2CO (Im = imidazole) and mer, cis-RuCl3(DMSO)(DMSO)(NH3)

Inorganica Chimica Acta · 1993 · Vol. 203(2) · pp. 205–217
Enzo AlessioGabriele BalducciAlberto LutmanG. MestroniM. CalligarisWahib M. Attia
Metal complexes synthesis and propertiesInorganic and Organometallic ChemistryMolecular Sensors and Ion DetectionChemistryTriclinic crystal systemMonoclinic crystal systemRutheniumCrystal structureSulfoxideCrystallographyStereochemistryLigand (biochemistry)Trans effect
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