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Efficient Proline-Catalyzed Michael Additions of Unmodified Ketones to Nitro Olefins
Organic Letters · 2001 · Vol. 3(16) · pp. 2423–2425
Benjamin List✉(Scripps Research Institute)Peter Pojarliev(Scripps Research Institute)Harry J. Martin(Scripps Research Institute)
Abstract
[reaction: see text] Here we describe the proline-catalyzed Michael addition of unmodified ketones to nitro olefins. This novel reaction provides gamma-nitro ketones in modest enantioselectivity yet excellent yields.
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