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Transition-Metal-Catalyzed Regioselective Arylation and Vinylation of Carboxylic Acids
Synthesis · 2010 · Vol. 2010(20) · pp. 3395–3409
Tetsuya Satoh✉(Osaka University)Masahiro Miura(Osaka University)
Abstract
Arene and heteroarene carboxylic acids undergo regioselective arylation and vinylation reactions at the positions ortho (cine) and ipso to their carboxyl function under transition-metal catalysis; these reactions are accompanied by carbon-hydrogen and carbon-carbon bond cleavages, respectively. Recent progress in this area is summarized in this article.
Catalytic C–H Functionalization MethodsCatalytic Cross-Coupling ReactionsAsymmetric Hydrogenation and CatalysisChemistryRegioselectivityCatalysisTransition metalCarbon fibersCarbon–hydrogen bond activationOrganic chemistryCombinatorial chemistry
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