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Mechanical Properties of Poly(lactic acid)/Starch Composites Compatibilized by Maleic Anhydride

Biomacromolecules · 2004 · Vol. 5(4) · pp. 1446–1451
Jianfeng ZhangXiuzhi Susan Sun

Abstract

Blending poly(lactic acid) (PLA) with wheat starch compatibized by maleic anhydride (MA) was performed with a lab-scale co-extruder. An initiator, 2,5-bis(tert-butylperoxy)-2,5 dimethylhexane (L101), was used to improve compatability among PLA, starch and MA. Interfacial adhesion between PLA and starch was significantly improved. Mechanical properties increased markedly compared to the virgin composites of PLA/starch. The PLA/starch composites at a constant ratio of 55/45 compatibilized by 1% MA and initiated by 10% L101 (MA basis) resulted in the highest tensile strength and elongation.

biodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysisMicroplastics and Plastic PollutionMaleic anhydrideStarchUltimate tensile strengthLactic acidPlastics extrusionMaterials scienceElongationComposite materialIzod impact strength testPolymer chemistry

MeSH terms

Chemistry, PhysicalMaleic AnhydridesPolyestersPolymersStarchTensile StrengthMolecular StructureLactic AcidChemical Phenomena
Citations
488
FWCI
6.35
field-weighted impact
References
22
Percentile
96%
vs. same field & year
Citations per year
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References
Thermal characterization of polylactides
Polymer · 1988 · 679 citations
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