articleTop 10% cited
Cobalt-Catalyzed Aryl−Sulfur Bond Formation
Organic Letters · 2006 · Vol. 8(24) · pp. 5613–5616
Ying‐Chieh Wong✉(National Tsing Hua University)Thiruvellore Thatai Jayanth(National Tsing Hua University)Chien‐Hong Cheng(National Tsing Hua University)
Abstract
A new cobalt-catalyzed coupling of aryl halides with thiophenols and alkanethiols is reported. A variety of aryl sulfides can be prepared in excellent yields under mild reaction conditions using 1-2 mol % of CoI2(dppe) and Zn. This new cobalt-catalyzed coupling represents an interesting addition to previously known methods to synthesize thioethers. [reaction: see text].
Sulfur-Based Synthesis TechniquesChemical Synthesis and ReactionsRadical Photochemical ReactionsChemistryArylCobaltCatalysisSulfurMedicinal chemistryCombinatorial chemistryPolymer chemistryOrganic chemistryAlkyl
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References
Tetrahedron report number 163
Tetrahedron · 1984 · 2,240 citations
A General Method for the Formation of Aryl−Sulfur Bonds Using Copper(I) Catalysts
Organic Letters · 2002 · 383 citations
Modern Synthetic Methods for Copper‐Mediated C(aryl)O, C(aryl)N, and C(aryl)S Bond Formation
Angewandte Chemie International Edition · 2003 · 2,521 citations
Modern Synthetic Methods for Copper‐Mediated C(aryl)O, C(aryl)N, and C(aryl)S Bond Formation
Angewandte Chemie International Edition · 2004 · 2,147 citations
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