Theory of anisotropic hyperfine interactions in<i>π</i>-electron radicals

Abstract

Abstract Anisotropic proton hyperfine interactions in π-electron radicals are approximated by a magnetic dipole interaction between each proton and an electron spin magnetization that is distributed in 2s and 2p Slater atomic orbitals centred on carbon atoms. On calcule de façon approchée les interactions hyperfines anisotropiques des protons dans les radicaux à électrons π au moyen d'une interaction dipolaire magnétique entre chaque proton et une magnétisation de spin électronique qui est répartie dans des orbitales atomiques de Slater, 2s et 2p, centrées sur les atomes de carbone. Anisotrope Hyperfein-Wechselwirkungen in π-Elektronenradikalen werden angenähert beschrieben durch eine magnetische Dipol-Wechselwirkung zwischen jedem Proton, sowie eine Elektron-Spin-Magnetisierung die über 2s- und 2p-Atomzustände nach Slater verteilt ist, welche um die Kohlenstoffatome konzentriert sind. Sponsored in part by the Office of Ordnance Research, U.S. Army, and by the United States Public Health Service. Sponsored in part by the Office of Ordnance Research, U.S. Army, and by the United States Public Health Service. Notes Sponsored in part by the Office of Ordnance Research, U.S. Army, and by the United States Public Health Service. Additional informationNotes on contributorsHarden M. McConnell Alfred P. Sloan Fellow.