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Electrochemical Polarization

Journal of The Electrochemical Society · 1957 · Vol. 104(1) · pp. 56–56

Milton R. Stern✉(Union Carbide (United States))A. L. Geaby(Union Carbide (United States))

Abstract

At low overvoltage values, deviations from Tafel behavior for a noncorroding electrode are due primarily to the reverse reaction of the oxidation‐reduction system, and at high overvoltages to concentration and/or resistance polarization. It is shown further that the practice of placing straight lines through a few experimental points is extremely hazardous, while the indiscriminate introduction of "breaks" is contrary to the electrode kinetics described.

Conducting polymers and applications Electrochemical Analysis and Applications Analytical Chemistry and SensorsTafel equationPolarization (electrochemistry)ElectrodeElectrochemistryOvervoltageMaterials scienceAnalytical Chemistry (journal)CorrosionChemistryVoltage

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